Waste Corn-Cob Cellulose Supported Copper Catalyst for Click and Aza-Michael Reactions

We prepared a highly active cellulose supported poly(amidoxime) Cu-catalyst 2 by the surface modification of waste corn-cob cellulose through graft copolymerization process (Scheme 1). The Cu-catalyst 2 was efficiently promoted the click reaction1 of organic azides and terminal alkynes including the...

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Main Authors:	Sarkar, Shaheen M., Sultana, Tahnim, Biswas, Tapan Kumar, Lutfor, M. R., M. M., Yusoff
Format:	Article
Language:	English
Published:	Royal Society of Chemistry 2016
Subjects:	Q Science (General) QD Chemistry
Online Access:	http://umpir.ump.edu.my/id/eprint/6727/ http://umpir.ump.edu.my/id/eprint/6727/ http://umpir.ump.edu.my/id/eprint/6727/ http://umpir.ump.edu.my/id/eprint/6727/1/Waste%20Corn-Cob%20Cellulose%20Supported%20Copper%20Catalyst%20for%20Click%20and%20Aza-Michael%20Reactions.pdf

id	ump-6727
recordtype	eprints
spelling	ump-67272020-02-21T08:09:21Z http://umpir.ump.edu.my/id/eprint/6727/ Waste Corn-Cob Cellulose Supported Copper Catalyst for Click and Aza-Michael Reactions Sarkar, Shaheen M. Sultana, Tahnim Biswas, Tapan Kumar Lutfor, M. R. M. M., Yusoff Q Science (General) QD Chemistry We prepared a highly active cellulose supported poly(amidoxime) Cu-catalyst 2 by the surface modification of waste corn-cob cellulose through graft copolymerization process (Scheme 1). The Cu-catalyst 2 was efficiently promoted the click reaction1 of organic azides and terminal alkynes including the three-component cyclization of a variety of alkynes, organic halides, and sodium azide (Scheme 2). The catalyst with 50 mol ppm (0.00050 mol%) to 0.05 mol% Cu promoted the cycloaddition with a TON of up to >18800, and was reused four times without loss of catalytic activity. Moreover the catalyst was also promoted the Aza-Michael reaction of aliphatic amines with a variety of olefins to give the corresponding products in up to 97% yield. Royal Society of Chemistry 2016 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/6727/1/Waste%20Corn-Cob%20Cellulose%20Supported%20Copper%20Catalyst%20for%20Click%20and%20Aza-Michael%20Reactions.pdf Sarkar, Shaheen M. and Sultana, Tahnim and Biswas, Tapan Kumar and Lutfor, M. R. and M. M., Yusoff (2016) Waste Corn-Cob Cellulose Supported Copper Catalyst for Click and Aza-Michael Reactions. New Journal of Chemistry, 60 (1). pp. 497-502. ISSN 1144-0546 http://dx.doi.org/10.1039/C5NJ02437D DOI: 10.1039/C5NJ02437D
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
language	English
topic	Q Science (General) QD Chemistry
spellingShingle	Q Science (General) QD Chemistry Sarkar, Shaheen M. Sultana, Tahnim Biswas, Tapan Kumar Lutfor, M. R. M. M., Yusoff Waste Corn-Cob Cellulose Supported Copper Catalyst for Click and Aza-Michael Reactions
description	We prepared a highly active cellulose supported poly(amidoxime) Cu-catalyst 2 by the surface modification of waste corn-cob cellulose through graft copolymerization process (Scheme 1). The Cu-catalyst 2 was efficiently promoted the click reaction1 of organic azides and terminal alkynes including the three-component cyclization of a variety of alkynes, organic halides, and sodium azide (Scheme 2). The catalyst with 50 mol ppm (0.00050 mol%) to 0.05 mol% Cu promoted the cycloaddition with a TON of up to >18800, and was reused four times without loss of catalytic activity. Moreover the catalyst was also promoted the Aza-Michael reaction of aliphatic amines with a variety of olefins to give the corresponding products in up to 97% yield.
format	Article
author	Sarkar, Shaheen M. Sultana, Tahnim Biswas, Tapan Kumar Lutfor, M. R. M. M., Yusoff
author_facet	Sarkar, Shaheen M. Sultana, Tahnim Biswas, Tapan Kumar Lutfor, M. R. M. M., Yusoff
author_sort	Sarkar, Shaheen M.
title	Waste Corn-Cob Cellulose Supported Copper Catalyst for Click and Aza-Michael Reactions
title_short	Waste Corn-Cob Cellulose Supported Copper Catalyst for Click and Aza-Michael Reactions
title_full	Waste Corn-Cob Cellulose Supported Copper Catalyst for Click and Aza-Michael Reactions
title_fullStr	Waste Corn-Cob Cellulose Supported Copper Catalyst for Click and Aza-Michael Reactions
title_full_unstemmed	Waste Corn-Cob Cellulose Supported Copper Catalyst for Click and Aza-Michael Reactions
title_sort	waste corn-cob cellulose supported copper catalyst for click and aza-michael reactions
publisher	Royal Society of Chemistry
publishDate	2016
url	http://umpir.ump.edu.my/id/eprint/6727/ http://umpir.ump.edu.my/id/eprint/6727/ http://umpir.ump.edu.my/id/eprint/6727/ http://umpir.ump.edu.my/id/eprint/6727/1/Waste%20Corn-Cob%20Cellulose%20Supported%20Copper%20Catalyst%20for%20Click%20and%20Aza-Michael%20Reactions.pdf
first_indexed	2023-09-18T22:02:44Z
last_indexed	2023-09-18T22:02:44Z
_version_	1777414506787373056

Waste Corn-Cob Cellulose Supported Copper Catalyst for Click and Aza-Michael Reactions

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