Mesoporous Silica-Supported Sulfonyldiamine Ligand for Microwave-Assisted Transfer Hydrogenation

N-Sulfonyl-1,2-diamine ligands, derived from 1,2-diaminocyclohexane and 1,2-diaminopropane, were immobilized onto mesoporous SBA-15 silica. The SBA-15-supported sulfonyldiamine-Ru complex was prepared in situ under microwave heating at 60 W for 3 min. The prepared sulfonyldiamine-Ru complex was used...

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Main Authors:	Sarkar, Shaheen M., Md. Eaqub, Ali, Islam, Md. Shahrul, Lutfor, M. R., Rashid, S. S., Karim, Md. Rezaul, M. M., Yusoff
Format:	Article
Language:	English
Published:	Hindawi Publishing Corporation 2015
Subjects:	Q Science (General)
Online Access:	http://umpir.ump.edu.my/id/eprint/7466/ http://umpir.ump.edu.my/id/eprint/7466/ http://umpir.ump.edu.my/id/eprint/7466/ http://umpir.ump.edu.my/id/eprint/7466/1/Mesoporous_Silica-Supported_Sulfonyldiamine_Ligand_for_Microwave-Assisted_Transfer_Hydrogenation.pdf

id	ump-7466
recordtype	eprints
spelling	ump-74662018-02-14T04:06:47Z http://umpir.ump.edu.my/id/eprint/7466/ Mesoporous Silica-Supported Sulfonyldiamine Ligand for Microwave-Assisted Transfer Hydrogenation Sarkar, Shaheen M. Md. Eaqub, Ali Islam, Md. Shahrul Lutfor, M. R. Rashid, S. S. Karim, Md. Rezaul M. M., Yusoff Q Science (General) N-Sulfonyl-1,2-diamine ligands, derived from 1,2-diaminocyclohexane and 1,2-diaminopropane, were immobilized onto mesoporous SBA-15 silica. The SBA-15-supported sulfonyldiamine-Ru complex was prepared in situ under microwave heating at 60 W for 3 min. The prepared sulfonyldiamine-Ru complex was used as an efficient catalyst for the transfer hydrogenation of ketones to the corresponding secondary alcohols. The heterogeneous complex showed extremely high catalytic activity with 99% conversion rate under microwave heating condition. The complexes were regenerated by simple filtration and reused two times without significant loss of activity. Hindawi Publishing Corporation 2015 Article PeerReviewed application/pdf en cc_by http://umpir.ump.edu.my/id/eprint/7466/1/Mesoporous_Silica-Supported_Sulfonyldiamine_Ligand_for_Microwave-Assisted_Transfer_Hydrogenation.pdf Sarkar, Shaheen M. and Md. Eaqub, Ali and Islam, Md. Shahrul and Lutfor, M. R. and Rashid, S. S. and Karim, Md. Rezaul and M. M., Yusoff (2015) Mesoporous Silica-Supported Sulfonyldiamine Ligand for Microwave-Assisted Transfer Hydrogenation. Journal of Nanomaterials, 2015 (674752). pp. 1-6. ISSN 1687-4110 (print); 1687-4129 (online) http://dx.doi.org/10.1155/2015/674752 DOI: 10.1155/2015/674752
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
language	English
topic	Q Science (General)
spellingShingle	Q Science (General) Sarkar, Shaheen M. Md. Eaqub, Ali Islam, Md. Shahrul Lutfor, M. R. Rashid, S. S. Karim, Md. Rezaul M. M., Yusoff Mesoporous Silica-Supported Sulfonyldiamine Ligand for Microwave-Assisted Transfer Hydrogenation
description	N-Sulfonyl-1,2-diamine ligands, derived from 1,2-diaminocyclohexane and 1,2-diaminopropane, were immobilized onto mesoporous SBA-15 silica. The SBA-15-supported sulfonyldiamine-Ru complex was prepared in situ under microwave heating at 60 W for 3 min. The prepared sulfonyldiamine-Ru complex was used as an efficient catalyst for the transfer hydrogenation of ketones to the corresponding secondary alcohols. The heterogeneous complex showed extremely high catalytic activity with 99% conversion rate under microwave heating condition. The complexes were regenerated by simple filtration and reused two times without significant loss of activity.
format	Article
author	Sarkar, Shaheen M. Md. Eaqub, Ali Islam, Md. Shahrul Lutfor, M. R. Rashid, S. S. Karim, Md. Rezaul M. M., Yusoff
author_facet	Sarkar, Shaheen M. Md. Eaqub, Ali Islam, Md. Shahrul Lutfor, M. R. Rashid, S. S. Karim, Md. Rezaul M. M., Yusoff
author_sort	Sarkar, Shaheen M.
title	Mesoporous Silica-Supported Sulfonyldiamine Ligand for Microwave-Assisted Transfer Hydrogenation
title_short	Mesoporous Silica-Supported Sulfonyldiamine Ligand for Microwave-Assisted Transfer Hydrogenation
title_full	Mesoporous Silica-Supported Sulfonyldiamine Ligand for Microwave-Assisted Transfer Hydrogenation
title_fullStr	Mesoporous Silica-Supported Sulfonyldiamine Ligand for Microwave-Assisted Transfer Hydrogenation
title_full_unstemmed	Mesoporous Silica-Supported Sulfonyldiamine Ligand for Microwave-Assisted Transfer Hydrogenation
title_sort	mesoporous silica-supported sulfonyldiamine ligand for microwave-assisted transfer hydrogenation
publisher	Hindawi Publishing Corporation
publishDate	2015
url	http://umpir.ump.edu.my/id/eprint/7466/ http://umpir.ump.edu.my/id/eprint/7466/ http://umpir.ump.edu.my/id/eprint/7466/ http://umpir.ump.edu.my/id/eprint/7466/1/Mesoporous_Silica-Supported_Sulfonyldiamine_Ligand_for_Microwave-Assisted_Transfer_Hydrogenation.pdf
first_indexed	2023-09-18T22:04:05Z
last_indexed	2023-09-18T22:04:05Z
_version_	1777414591628705792

Mesoporous Silica-Supported Sulfonyldiamine Ligand for Microwave-Assisted Transfer Hydrogenation

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