Utilization of Waste Fat from Catfish (Pangasius) in Methyl Esters Preparation Using Cao Derived from Waste Marine Barnacle and Bivalve Clam as Solid Catalysts

The use of waste oils/fats, as well as catalyst from waste materials, for producing methyl esters (biodiesel) via transesterification has been research of recent interest. In the present work, the transesterification of waste catfish fat using barnacle and bivalve clam as a heterogeneous catalyst wa...

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Main Authors:	Gaanty Pragas, Maniam, Noor, Hindryawati, Irma, Nurfitri, Intan Shafinaz, Abd Manaf, Neshabran, Ramachandran, Mohd Hasbi, Ab. Rahim
Format:	Article
Language:	English
Published:	Elsevier Ltd 2015
Subjects:	Q Science (General)
Online Access:	http://umpir.ump.edu.my/id/eprint/7862/ http://umpir.ump.edu.my/id/eprint/7862/ http://umpir.ump.edu.my/id/eprint/7862/ http://umpir.ump.edu.my/id/eprint/7862/1/Utilization_of_waste_fat_from_catfish_%28Pangasius%29_in_methyl_esters_preparation_using_CaO_derived_from_waste_marine_barnacle_and_bivalve_clam_as_solid_catalysts.pdf

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spelling	ump-78622018-11-22T08:11:13Z http://umpir.ump.edu.my/id/eprint/7862/ Utilization of Waste Fat from Catfish (Pangasius) in Methyl Esters Preparation Using Cao Derived from Waste Marine Barnacle and Bivalve Clam as Solid Catalysts Gaanty Pragas, Maniam Noor, Hindryawati Irma, Nurfitri Intan Shafinaz, Abd Manaf Neshabran, Ramachandran Mohd Hasbi, Ab. Rahim Q Science (General) The use of waste oils/fats, as well as catalyst from waste materials, for producing methyl esters (biodiesel) via transesterification has been research of recent interest. In the present work, the transesterification of waste catfish fat using barnacle and bivalve clam as a heterogeneous catalyst was attempted. X-ray diffraction and FTIR results show that, upon thermal activation, both shells transformed into CaO, the active ingredient that catalyzes the reaction. In addition, the results showed that the methyl esters (ME) content of reaction catalyzed by barnacle and bivalve clam were at 97.6 ± 0.03 and 92.0 ± 0.05%, respectively in 3 h reaction duration at 65 °C. Optimization of reaction parameters revealed that MeOH:oi at 12:1 (molar) and catalyst at 4 wt.% as an optimal reaction conditions for both catalysts. Furthermore, the catalysts can be reused for four cycles while maintaining ME content above 90%. Elsevier Ltd 2015 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/7862/1/Utilization_of_waste_fat_from_catfish_%28Pangasius%29_in_methyl_esters_preparation_using_CaO_derived_from_waste_marine_barnacle_and_bivalve_clam_as_solid_catalysts.pdf Gaanty Pragas, Maniam and Noor, Hindryawati and Irma, Nurfitri and Intan Shafinaz, Abd Manaf and Neshabran, Ramachandran and Mohd Hasbi, Ab. Rahim (2015) Utilization of Waste Fat from Catfish (Pangasius) in Methyl Esters Preparation Using Cao Derived from Waste Marine Barnacle and Bivalve Clam as Solid Catalysts. Journal of the Taiwan Institute of Chemical Engineers, 49. pp. 58-66. ISSN 1876-1070 http://dx.doi.org/10.1016/j.jtice.2014.11.010 DOI: 10.1016/j.jtice.2014.11.010
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
language	English
topic	Q Science (General)
spellingShingle	Q Science (General) Gaanty Pragas, Maniam Noor, Hindryawati Irma, Nurfitri Intan Shafinaz, Abd Manaf Neshabran, Ramachandran Mohd Hasbi, Ab. Rahim Utilization of Waste Fat from Catfish (Pangasius) in Methyl Esters Preparation Using Cao Derived from Waste Marine Barnacle and Bivalve Clam as Solid Catalysts
description	The use of waste oils/fats, as well as catalyst from waste materials, for producing methyl esters (biodiesel) via transesterification has been research of recent interest. In the present work, the transesterification of waste catfish fat using barnacle and bivalve clam as a heterogeneous catalyst was attempted. X-ray diffraction and FTIR results show that, upon thermal activation, both shells transformed into CaO, the active ingredient that catalyzes the reaction. In addition, the results showed that the methyl esters (ME) content of reaction catalyzed by barnacle and bivalve clam were at 97.6 ± 0.03 and 92.0 ± 0.05%, respectively in 3 h reaction duration at 65 °C. Optimization of reaction parameters revealed that MeOH:oi at 12:1 (molar) and catalyst at 4 wt.% as an optimal reaction conditions for both catalysts. Furthermore, the catalysts can be reused for four cycles while maintaining ME content above 90%.
format	Article
author	Gaanty Pragas, Maniam Noor, Hindryawati Irma, Nurfitri Intan Shafinaz, Abd Manaf Neshabran, Ramachandran Mohd Hasbi, Ab. Rahim
author_facet	Gaanty Pragas, Maniam Noor, Hindryawati Irma, Nurfitri Intan Shafinaz, Abd Manaf Neshabran, Ramachandran Mohd Hasbi, Ab. Rahim
author_sort	Gaanty Pragas, Maniam
title	Utilization of Waste Fat from Catfish (Pangasius) in Methyl Esters Preparation Using Cao Derived from Waste Marine Barnacle and Bivalve Clam as Solid Catalysts
title_short	Utilization of Waste Fat from Catfish (Pangasius) in Methyl Esters Preparation Using Cao Derived from Waste Marine Barnacle and Bivalve Clam as Solid Catalysts
title_full	Utilization of Waste Fat from Catfish (Pangasius) in Methyl Esters Preparation Using Cao Derived from Waste Marine Barnacle and Bivalve Clam as Solid Catalysts
title_fullStr	Utilization of Waste Fat from Catfish (Pangasius) in Methyl Esters Preparation Using Cao Derived from Waste Marine Barnacle and Bivalve Clam as Solid Catalysts
title_full_unstemmed	Utilization of Waste Fat from Catfish (Pangasius) in Methyl Esters Preparation Using Cao Derived from Waste Marine Barnacle and Bivalve Clam as Solid Catalysts
title_sort	utilization of waste fat from catfish (pangasius) in methyl esters preparation using cao derived from waste marine barnacle and bivalve clam as solid catalysts
publisher	Elsevier Ltd
publishDate	2015
url	http://umpir.ump.edu.my/id/eprint/7862/ http://umpir.ump.edu.my/id/eprint/7862/ http://umpir.ump.edu.my/id/eprint/7862/ http://umpir.ump.edu.my/id/eprint/7862/1/Utilization_of_waste_fat_from_catfish_%28Pangasius%29_in_methyl_esters_preparation_using_CaO_derived_from_waste_marine_barnacle_and_bivalve_clam_as_solid_catalysts.pdf
first_indexed	2023-09-18T22:04:56Z
last_indexed	2023-09-18T22:04:56Z
_version_	1777414645245542400

Utilization of Waste Fat from Catfish (Pangasius) in Methyl Esters Preparation Using Cao Derived from Waste Marine Barnacle and Bivalve Clam as Solid Catalysts

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