Melt Blends of Poly(lactic acid)/Natural Rubber and Liquid Epoxidised Natural Rubber

Although poly(lactic acid) (PLA) is among widely used biodegradable polymers, it has limited applications due to its inherent brittleness, low elongation at break and toughness. Blending with natural rubber (NR) and epoxidised natural rubber (ENR) seems to be a promising alternative, as both materia...

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Main Authors: Mohd Bijarimi, Mat Piah, Sahrim, Ahmad, Rozaidi, Rasid
Format: Article
Language:English
Published: Malaysian Rubber Board 2014
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/8030/
http://umpir.ump.edu.my/id/eprint/8030/
http://umpir.ump.edu.my/id/eprint/8030/1/fkksa-2014-Bijarimi-Melt_Blends_of_Poly%28lactic_acid%29.pdf
id ump-8030
recordtype eprints
spelling ump-80302018-07-16T08:14:02Z http://umpir.ump.edu.my/id/eprint/8030/ Melt Blends of Poly(lactic acid)/Natural Rubber and Liquid Epoxidised Natural Rubber Mohd Bijarimi, Mat Piah Sahrim, Ahmad Rozaidi, Rasid TP Chemical technology Although poly(lactic acid) (PLA) is among widely used biodegradable polymers, it has limited applications due to its inherent brittleness, low elongation at break and toughness. Blending with natural rubber (NR) and epoxidised natural rubber (ENR) seems to be a promising alternative, as both materials are derived from renewable resources. Natural rubber was melt-blended with poly(lactic acid) in an internal mixer, Haake Rheomix, with a rotor speed of 50 r.p.m. at 180ºC. Liquid epoxidised natural rubber (LENR) was used as a compatibiliser in the binary blending system of thermoplastic natural rubber (TPNR). Results indicate that the mixing torque value and stabilisation torque value in LENR blends are lower than in blends without the compatibiliser. Various compositions of natural rubber, epoxidised natural rubber and compatibiliser were investigated with respect to the stress-strain behaviour. It was found that the addition of LENR compatibiliser improved the stress at break and Young’s modulus in the blend system of 40/60 PLA/rubber compositions. The increase in stress at break and Young’s modulus were associated with the ability of LENR to compatibilise the PLA/NR binary blends. Malaysian Rubber Board 2014 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/8030/1/fkksa-2014-Bijarimi-Melt_Blends_of_Poly%28lactic_acid%29.pdf Mohd Bijarimi, Mat Piah and Sahrim, Ahmad and Rozaidi, Rasid (2014) Melt Blends of Poly(lactic acid)/Natural Rubber and Liquid Epoxidised Natural Rubber. Journal of Rubber Research, 17 (2). pp. 57-68. ISSN 1511-1768 http://rios.lgm.gov.my/cms/journalChildDetails.jsp?childKey=vital1\:86409&title=Journal%20of%20Rubber%20Research
repository_type Digital Repository
institution_category Local University
institution Universiti Malaysia Pahang
building UMP Institutional Repository
collection Online Access
language English
topic TP Chemical technology
spellingShingle TP Chemical technology
Mohd Bijarimi, Mat Piah
Sahrim, Ahmad
Rozaidi, Rasid
Melt Blends of Poly(lactic acid)/Natural Rubber and Liquid Epoxidised Natural Rubber
description Although poly(lactic acid) (PLA) is among widely used biodegradable polymers, it has limited applications due to its inherent brittleness, low elongation at break and toughness. Blending with natural rubber (NR) and epoxidised natural rubber (ENR) seems to be a promising alternative, as both materials are derived from renewable resources. Natural rubber was melt-blended with poly(lactic acid) in an internal mixer, Haake Rheomix, with a rotor speed of 50 r.p.m. at 180ºC. Liquid epoxidised natural rubber (LENR) was used as a compatibiliser in the binary blending system of thermoplastic natural rubber (TPNR). Results indicate that the mixing torque value and stabilisation torque value in LENR blends are lower than in blends without the compatibiliser. Various compositions of natural rubber, epoxidised natural rubber and compatibiliser were investigated with respect to the stress-strain behaviour. It was found that the addition of LENR compatibiliser improved the stress at break and Young’s modulus in the blend system of 40/60 PLA/rubber compositions. The increase in stress at break and Young’s modulus were associated with the ability of LENR to compatibilise the PLA/NR binary blends.
format Article
author Mohd Bijarimi, Mat Piah
Sahrim, Ahmad
Rozaidi, Rasid
author_facet Mohd Bijarimi, Mat Piah
Sahrim, Ahmad
Rozaidi, Rasid
author_sort Mohd Bijarimi, Mat Piah
title Melt Blends of Poly(lactic acid)/Natural Rubber and Liquid Epoxidised Natural Rubber
title_short Melt Blends of Poly(lactic acid)/Natural Rubber and Liquid Epoxidised Natural Rubber
title_full Melt Blends of Poly(lactic acid)/Natural Rubber and Liquid Epoxidised Natural Rubber
title_fullStr Melt Blends of Poly(lactic acid)/Natural Rubber and Liquid Epoxidised Natural Rubber
title_full_unstemmed Melt Blends of Poly(lactic acid)/Natural Rubber and Liquid Epoxidised Natural Rubber
title_sort melt blends of poly(lactic acid)/natural rubber and liquid epoxidised natural rubber
publisher Malaysian Rubber Board
publishDate 2014
url http://umpir.ump.edu.my/id/eprint/8030/
http://umpir.ump.edu.my/id/eprint/8030/
http://umpir.ump.edu.my/id/eprint/8030/1/fkksa-2014-Bijarimi-Melt_Blends_of_Poly%28lactic_acid%29.pdf
first_indexed 2023-09-18T22:05:17Z
last_indexed 2023-09-18T22:05:17Z
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