Highly Active Thiol-functionalized SBA-15 Supported Palladium catalyst for Sonogashira and Suzuki-Miyaura Cross-coupling Reactions
Highly ordered mesoporous silica SBA-15 with pendent 3-mercaptopropyl groups has been prepared by condensation of surface silanols and (3-mercaptopropyl)trimethoxysilane. Treatment of the mercaptopropylated SBA-15 with (CH3CN)2PdCl2 gave a heterogeneous Pd-catalyst. The immobilized Pd-catalyst se...
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Royal Society of Chemistry
2015
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| Online Access: | http://umpir.ump.edu.my/id/eprint/8101/ http://umpir.ump.edu.my/id/eprint/8101/ http://umpir.ump.edu.my/id/eprint/8101/ |
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ump-81012018-02-14T04:01:50Z http://umpir.ump.edu.my/id/eprint/8101/ Highly Active Thiol-functionalized SBA-15 Supported Palladium catalyst for Sonogashira and Suzuki-Miyaura Cross-coupling Reactions Sarkar, Shaheen M. Lutfor, M. R. M. M., Yusoff Q Science (General) Highly ordered mesoporous silica SBA-15 with pendent 3-mercaptopropyl groups has been prepared by condensation of surface silanols and (3-mercaptopropyl)trimethoxysilane. Treatment of the mercaptopropylated SBA-15 with (CH3CN)2PdCl2 gave a heterogeneous Pd-catalyst. The immobilized Pd-catalyst served as an efficient heterogeneous catalyst for Sonogashira and SuzukiâÂÂMiyaura cross coupling reactions of aryl halides. Furthermore, the SBA-15 supported Pd-catalyst was recovered by a simple filtration from the reaction mixture and reused five times without significant loss of its catalytic activity. Royal Society of Chemistry 2015 Article PeerReviewed Sarkar, Shaheen M. and Lutfor, M. R. and M. M., Yusoff (2015) Highly Active Thiol-functionalized SBA-15 Supported Palladium catalyst for Sonogashira and Suzuki-Miyaura Cross-coupling Reactions. RSC Advances, 5. pp. 1295-1300. ISSN 2046-2069 http://dx.doi.org/10.1039/C4RA13322F DOI: 10.1039/C4RA13322F |
| repository_type |
Digital Repository |
| institution_category |
Local University |
| institution |
Universiti Malaysia Pahang |
| building |
UMP Institutional Repository |
| collection |
Online Access |
| topic |
Q Science (General) |
| spellingShingle |
Q Science (General) Sarkar, Shaheen M. Lutfor, M. R. M. M., Yusoff Highly Active Thiol-functionalized SBA-15 Supported Palladium catalyst for Sonogashira and Suzuki-Miyaura Cross-coupling Reactions |
| description |
Highly ordered mesoporous silica SBA-15 with pendent 3-mercaptopropyl groups has been prepared by
condensation of surface silanols and (3-mercaptopropyl)trimethoxysilane. Treatment of the
mercaptopropylated SBA-15 with (CH3CN)2PdCl2 gave a heterogeneous Pd-catalyst. The immobilized
Pd-catalyst served as an efficient heterogeneous catalyst for Sonogashira and SuzukiâÂÂMiyaura cross
coupling reactions of aryl halides. Furthermore, the SBA-15 supported Pd-catalyst was recovered by a
simple filtration from the reaction mixture and reused five times without significant loss of its catalytic
activity. |
| format |
Article |
| author |
Sarkar, Shaheen M. Lutfor, M. R. M. M., Yusoff |
| author_facet |
Sarkar, Shaheen M. Lutfor, M. R. M. M., Yusoff |
| author_sort |
Sarkar, Shaheen M. |
| title |
Highly Active Thiol-functionalized SBA-15 Supported Palladium catalyst for Sonogashira and Suzuki-Miyaura Cross-coupling Reactions
|
| title_short |
Highly Active Thiol-functionalized SBA-15 Supported Palladium catalyst for Sonogashira and Suzuki-Miyaura Cross-coupling Reactions
|
| title_full |
Highly Active Thiol-functionalized SBA-15 Supported Palladium catalyst for Sonogashira and Suzuki-Miyaura Cross-coupling Reactions
|
| title_fullStr |
Highly Active Thiol-functionalized SBA-15 Supported Palladium catalyst for Sonogashira and Suzuki-Miyaura Cross-coupling Reactions
|
| title_full_unstemmed |
Highly Active Thiol-functionalized SBA-15 Supported Palladium catalyst for Sonogashira and Suzuki-Miyaura Cross-coupling Reactions
|
| title_sort |
highly active thiol-functionalized sba-15 supported palladium catalyst for sonogashira and suzuki-miyaura cross-coupling reactions |
| publisher |
Royal Society of Chemistry |
| publishDate |
2015 |
| url |
http://umpir.ump.edu.my/id/eprint/8101/ http://umpir.ump.edu.my/id/eprint/8101/ http://umpir.ump.edu.my/id/eprint/8101/ |
| first_indexed |
2023-09-18T22:05:24Z |
| last_indexed |
2023-09-18T22:05:24Z |
| _version_ |
1777414673824481280 |