Thermo-oxidative Degradation of High Density Polyethylene Containing Manganese Carboxylate

This paper reports the study of utilization of manganese laurate for accelerating the degradation process of high density polyethylene (HDPE). Specimens were prepared by loading manganese laurate from 0 to 1%(w/w) in HDPE resins using twin screw extruder followed by injection molding. Thermal treat...

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Main Authors:	Maryudi, M., Anwaruddin, Hisyam, R. M., Yunus, Beg, M. D. H.
Format:	Article
Language:	English
Published:	IJERA 2013
Subjects:	TP Chemical technology
Online Access:	http://umpir.ump.edu.my/id/eprint/8324/ http://umpir.ump.edu.my/id/eprint/8324/ http://umpir.ump.edu.my/id/eprint/8324/1/Thermo-oxidative_Degradation_of_High_Density_Polyethylene_Containing_Manganese_Carboxylate.pdf

id	ump-8324
recordtype	eprints
spelling	ump-83242018-01-10T04:01:49Z http://umpir.ump.edu.my/id/eprint/8324/ Thermo-oxidative Degradation of High Density Polyethylene Containing Manganese Carboxylate Maryudi, M. Anwaruddin, Hisyam R. M., Yunus Beg, M. D. H. TP Chemical technology This paper reports the study of utilization of manganese laurate for accelerating the degradation process of high density polyethylene (HDPE). Specimens were prepared by loading manganese laurate from 0 to 1%(w/w) in HDPE resins using twin screw extruder followed by injection molding. Thermal treatment was performed at 70C, for maximum duration of 1000 hours to examine the thermooxidative degradation of HDPE blends. Tensile testing, FTIR analysis, molecular weight analysis, melt flow index (MFI) analysis, differential scanning calorimetry (DSC) test, thermogravimetric analyzer (TGA) test, were carried out to assess the changes during treatment. The results reveal that sample containing manganese laurate are readily to undergo thermo-oxidative degradation under temperature condition of 70 C. Tensile strength and elongation at break decreased during treatment. Pure and HDPE containing 1 % of manganese laurate (ML10) samples have lost about 11.74 and 43.33% of tensile strength, and about 16.21 and 55.85 % of elongation at break respectively. FTIR traces exhibited that carbonyl group’s peak in the region 1700-1800 cm-1 arise during thermal treatment as the result of oxidation. Average molecular weights were found to decrease about 16.12 and 67.51% from their initial value for pure and ML10 samples respectively, and consequently MFI increased significantly. Thermal stability and melting temperature were found to shift to lower temperature, while crystallinity generally increased. The degradation rate of HDPE increased by increasing the amount of manganese laurate incorporated. IJERA 2013 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/8324/1/Thermo-oxidative_Degradation_of_High_Density_Polyethylene_Containing_Manganese_Carboxylate.pdf Maryudi, M. and Anwaruddin, Hisyam and R. M., Yunus and Beg, M. D. H. (2013) Thermo-oxidative Degradation of High Density Polyethylene Containing Manganese Carboxylate. International Journal of Engineering Research and Applications (IJERA), 3 (2). pp. 1156-1165. ISSN 2248-9622 http://www.ijera.com/papers/Vol3_issue2/GH3211561165.pdf
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
language	English
topic	TP Chemical technology
spellingShingle	TP Chemical technology Maryudi, M. Anwaruddin, Hisyam R. M., Yunus Beg, M. D. H. Thermo-oxidative Degradation of High Density Polyethylene Containing Manganese Carboxylate
description	This paper reports the study of utilization of manganese laurate for accelerating the degradation process of high density polyethylene (HDPE). Specimens were prepared by loading manganese laurate from 0 to 1%(w/w) in HDPE resins using twin screw extruder followed by injection molding. Thermal treatment was performed at 70C, for maximum duration of 1000 hours to examine the thermooxidative degradation of HDPE blends. Tensile testing, FTIR analysis, molecular weight analysis, melt flow index (MFI) analysis, differential scanning calorimetry (DSC) test, thermogravimetric analyzer (TGA) test, were carried out to assess the changes during treatment. The results reveal that sample containing manganese laurate are readily to undergo thermo-oxidative degradation under temperature condition of 70 C. Tensile strength and elongation at break decreased during treatment. Pure and HDPE containing 1 % of manganese laurate (ML10) samples have lost about 11.74 and 43.33% of tensile strength, and about 16.21 and 55.85 % of elongation at break respectively. FTIR traces exhibited that carbonyl group’s peak in the region 1700-1800 cm-1 arise during thermal treatment as the result of oxidation. Average molecular weights were found to decrease about 16.12 and 67.51% from their initial value for pure and ML10 samples respectively, and consequently MFI increased significantly. Thermal stability and melting temperature were found to shift to lower temperature, while crystallinity generally increased. The degradation rate of HDPE increased by increasing the amount of manganese laurate incorporated.
format	Article
author	Maryudi, M. Anwaruddin, Hisyam R. M., Yunus Beg, M. D. H.
author_facet	Maryudi, M. Anwaruddin, Hisyam R. M., Yunus Beg, M. D. H.
author_sort	Maryudi, M.
title	Thermo-oxidative Degradation of High Density Polyethylene Containing Manganese Carboxylate
title_short	Thermo-oxidative Degradation of High Density Polyethylene Containing Manganese Carboxylate
title_full	Thermo-oxidative Degradation of High Density Polyethylene Containing Manganese Carboxylate
title_fullStr	Thermo-oxidative Degradation of High Density Polyethylene Containing Manganese Carboxylate
title_full_unstemmed	Thermo-oxidative Degradation of High Density Polyethylene Containing Manganese Carboxylate
title_sort	thermo-oxidative degradation of high density polyethylene containing manganese carboxylate
publisher	IJERA
publishDate	2013
url	http://umpir.ump.edu.my/id/eprint/8324/ http://umpir.ump.edu.my/id/eprint/8324/ http://umpir.ump.edu.my/id/eprint/8324/1/Thermo-oxidative_Degradation_of_High_Density_Polyethylene_Containing_Manganese_Carboxylate.pdf
first_indexed	2023-09-18T22:05:46Z
last_indexed	2023-09-18T22:05:46Z
_version_	1777414697468821504

Thermo-oxidative Degradation of High Density Polyethylene Containing Manganese Carboxylate

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