Formulation of Mixed-Matrix Membrane (PSF/Zeolite) for CO2/N2 Separation: Screening of Polymer Concentration

This research investigates the permeability of CO2 and N2 as well as selectivity of CO2 over N2 of polysulfone (PSF) mixed matrix membranes filled with zeolite 4Å particles. The membranes were prepared by solution-casting method and utilized to determine the permeation rates of N2 and CO2. It was ch...

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Main Authors:	Chen, Chee Lek, Sunarti, Abd Rahman
Format:	Article
Language:	English
Published:	Scientific Research 2015
Subjects:	TP Chemical technology
Online Access:	http://umpir.ump.edu.my/id/eprint/9282/ http://umpir.ump.edu.my/id/eprint/9282/ http://umpir.ump.edu.my/id/eprint/9282/ http://umpir.ump.edu.my/id/eprint/9282/1/Formulation%20of%20Mixed-Matrix%20Membrane%20%28PSF-Zeolite%29%20for%20CO2-N2%20Separation-%20Screening%20of%20Polymer%20Concentration.pdf

id	ump-9282
recordtype	eprints
spelling	ump-92822018-05-22T06:55:08Z http://umpir.ump.edu.my/id/eprint/9282/ Formulation of Mixed-Matrix Membrane (PSF/Zeolite) for CO2/N2 Separation: Screening of Polymer Concentration Chen, Chee Lek Sunarti, Abd Rahman TP Chemical technology This research investigates the permeability of CO2 and N2 as well as selectivity of CO2 over N2 of polysulfone (PSF) mixed matrix membranes filled with zeolite 4Å particles. The membranes were prepared by solution-casting method and utilized to determine the permeation rates of N2 and CO2. It was characterized by FTIR and the gas separation performance was analysed by Design of Expert (DOE) method. FTIR result revealed the intensity of peak for sulfone S=O vibration at 1322 cm-1; it was related to O=S=O bound of polysulfone in the sample. The single concentration variable has low outcome, however the mixture concentration interaction was effectively to lead better selectivity of CO2 over N2. In terms of interaction between mixture concentrations, interaction between PSF and N-Methyl-2-pyrrolidone (NMP) has considerable effect on the permeability of CO2 with the highest F value of 0.46 membrane. NMP exhibited a high degree of polarity and hydrogen bonding which led to effect of selective skin and permeation rate. The model regression equations were developed as the potential use for screening the permeability of CO2 and N2 based on the deviation effect of polymer concentration. Scientific Research 2015 Article PeerReviewed application/pdf en cc_by http://umpir.ump.edu.my/id/eprint/9282/1/Formulation%20of%20Mixed-Matrix%20Membrane%20%28PSF-Zeolite%29%20for%20CO2-N2%20Separation-%20Screening%20of%20Polymer%20Concentration.pdf Chen, Chee Lek and Sunarti, Abd Rahman (2015) Formulation of Mixed-Matrix Membrane (PSF/Zeolite) for CO2/N2 Separation: Screening of Polymer Concentration. Journal of Materials Science and Chemical Engineering, 3 (5). pp. 1-10. ISSN 2327-6045 (print); 2327-6053 (online) http://dx.doi.org/10.4236/msce.2015.35008 DOI: 10.4236/msce.2015.35008
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
language	English
topic	TP Chemical technology
spellingShingle	TP Chemical technology Chen, Chee Lek Sunarti, Abd Rahman Formulation of Mixed-Matrix Membrane (PSF/Zeolite) for CO2/N2 Separation: Screening of Polymer Concentration
description	This research investigates the permeability of CO2 and N2 as well as selectivity of CO2 over N2 of polysulfone (PSF) mixed matrix membranes filled with zeolite 4Å particles. The membranes were prepared by solution-casting method and utilized to determine the permeation rates of N2 and CO2. It was characterized by FTIR and the gas separation performance was analysed by Design of Expert (DOE) method. FTIR result revealed the intensity of peak for sulfone S=O vibration at 1322 cm-1; it was related to O=S=O bound of polysulfone in the sample. The single concentration variable has low outcome, however the mixture concentration interaction was effectively to lead better selectivity of CO2 over N2. In terms of interaction between mixture concentrations, interaction between PSF and N-Methyl-2-pyrrolidone (NMP) has considerable effect on the permeability of CO2 with the highest F value of 0.46 membrane. NMP exhibited a high degree of polarity and hydrogen bonding which led to effect of selective skin and permeation rate. The model regression equations were developed as the potential use for screening the permeability of CO2 and N2 based on the deviation effect of polymer concentration.
format	Article
author	Chen, Chee Lek Sunarti, Abd Rahman
author_facet	Chen, Chee Lek Sunarti, Abd Rahman
author_sort	Chen, Chee Lek
title	Formulation of Mixed-Matrix Membrane (PSF/Zeolite) for CO2/N2 Separation: Screening of Polymer Concentration
title_short	Formulation of Mixed-Matrix Membrane (PSF/Zeolite) for CO2/N2 Separation: Screening of Polymer Concentration
title_full	Formulation of Mixed-Matrix Membrane (PSF/Zeolite) for CO2/N2 Separation: Screening of Polymer Concentration
title_fullStr	Formulation of Mixed-Matrix Membrane (PSF/Zeolite) for CO2/N2 Separation: Screening of Polymer Concentration
title_full_unstemmed	Formulation of Mixed-Matrix Membrane (PSF/Zeolite) for CO2/N2 Separation: Screening of Polymer Concentration
title_sort	formulation of mixed-matrix membrane (psf/zeolite) for co2/n2 separation: screening of polymer concentration
publisher	Scientific Research
publishDate	2015
url	http://umpir.ump.edu.my/id/eprint/9282/ http://umpir.ump.edu.my/id/eprint/9282/ http://umpir.ump.edu.my/id/eprint/9282/ http://umpir.ump.edu.my/id/eprint/9282/1/Formulation%20of%20Mixed-Matrix%20Membrane%20%28PSF-Zeolite%29%20for%20CO2-N2%20Separation-%20Screening%20of%20Polymer%20Concentration.pdf
first_indexed	2023-09-18T22:07:42Z
last_indexed	2023-09-18T22:07:42Z
_version_	1777414818755510272

Formulation of Mixed-Matrix Membrane (PSF/Zeolite) for CO2/N2 Separation: Screening of Polymer Concentration

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