Pretreatment of Sludge Palm Oil (SPO) for biodiesel production by esterification

Sludge palm oil is a significant raw martial with above than 40% FFA for biodiesel production. The problem with processing these low cost oils is that they often contain large amounts of free fatty acids that cannot be converted to biodiesel using an alkaline catalyst. In this study, a comparison of...

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Main Authors:	Hayyan, Adeeb, Alam, Md. Zahangir, Kabbashi, Nassereldeen Ahmed, Mirghani, Mohamed Elwathig Saeed
Format:	Conference or Workshop Item
Language:	English
Published:	2008
Subjects:	TP Chemical technology TP315 Fuel
Online Access:	http://irep.iium.edu.my/5519/ http://irep.iium.edu.my/5519/1/adeeb_UKM_Ac1.pdf

id	iium-5519
recordtype	eprints
spelling	iium-55192012-05-08T00:35:49Z http://irep.iium.edu.my/5519/ Pretreatment of Sludge Palm Oil (SPO) for biodiesel production by esterification Hayyan, Adeeb Alam, Md. Zahangir Kabbashi, Nassereldeen Ahmed Mirghani, Mohamed Elwathig Saeed TP Chemical technology TP315 Fuel Sludge palm oil is a significant raw martial with above than 40% FFA for biodiesel production. The problem with processing these low cost oils is that they often contain large amounts of free fatty acids that cannot be converted to biodiesel using an alkaline catalyst. In this study, a comparison of acids catalyzed potential is described to reduce the free fatty acids content of these feed stocks. An acid-catalyzed was using in pretreatment of sludge palm oil with present alcohol to esterify the free fatty acids before trasestifying the triglycerides with an alkaline catalyst to complete the reaction. The process was performed with sludge palm oil containing 48% FFA. The types of an acids-catalyzed were two strong acid and weak acid (H2SO4, HCl and CH3COOH) wt/wt respectively. The reaction mixture was allowed to settle in order to calculate the yield of product in different ratio. Conditions of the process are followed a molar ratio methanol/oil 10:1 with stirrer speed of 400 rpm for 1 hr reaction time at 60 C. The study showed that acid level of the high free fatty acids feed stocks could be reduced from 48%FFA to less than 2% FFA using sulfuric acid and less than 7% FFA by using hydrochloric acid with large amount of water. But it is obvious that addition of acetic acid increased the free fatty acids. The samples after reducing the FFA below than 2%FFA the transesterification reaction were completed with an alkaline catalyst to produce biodiesel. 2008-12-02 Conference or Workshop Item PeerReviewed application/pdf en http://irep.iium.edu.my/5519/1/adeeb_UKM_Ac1.pdf Hayyan, Adeeb and Alam, Md. Zahangir and Kabbashi, Nassereldeen Ahmed and Mirghani, Mohamed Elwathig Saeed (2008) Pretreatment of Sludge Palm Oil (SPO) for biodiesel production by esterification. In: 22nd Symposium of Malaysian Chemical Engineers (SOMChE 2008), 2 - 3 December, 2008, Kuala Lumpur.
repository_type	Digital Repository
institution_category	Local University
institution	International Islamic University Malaysia
building	IIUM Repository
collection	Online Access
language	English
topic	TP Chemical technology TP315 Fuel
spellingShingle	TP Chemical technology TP315 Fuel Hayyan, Adeeb Alam, Md. Zahangir Kabbashi, Nassereldeen Ahmed Mirghani, Mohamed Elwathig Saeed Pretreatment of Sludge Palm Oil (SPO) for biodiesel production by esterification
description	Sludge palm oil is a significant raw martial with above than 40% FFA for biodiesel production. The problem with processing these low cost oils is that they often contain large amounts of free fatty acids that cannot be converted to biodiesel using an alkaline catalyst. In this study, a comparison of acids catalyzed potential is described to reduce the free fatty acids content of these feed stocks. An acid-catalyzed was using in pretreatment of sludge palm oil with present alcohol to esterify the free fatty acids before trasestifying the triglycerides with an alkaline catalyst to complete the reaction. The process was performed with sludge palm oil containing 48% FFA. The types of an acids-catalyzed were two strong acid and weak acid (H2SO4, HCl and CH3COOH) wt/wt respectively. The reaction mixture was allowed to settle in order to calculate the yield of product in different ratio. Conditions of the process are followed a molar ratio methanol/oil 10:1 with stirrer speed of 400 rpm for 1 hr reaction time at 60 C. The study showed that acid level of the high free fatty acids feed stocks could be reduced from 48%FFA to less than 2% FFA using sulfuric acid and less than 7% FFA by using hydrochloric acid with large amount of water. But it is obvious that addition of acetic acid increased the free fatty acids. The samples after reducing the FFA below than 2%FFA the transesterification reaction were completed with an alkaline catalyst to produce biodiesel.
format	Conference or Workshop Item
author	Hayyan, Adeeb Alam, Md. Zahangir Kabbashi, Nassereldeen Ahmed Mirghani, Mohamed Elwathig Saeed
author_facet	Hayyan, Adeeb Alam, Md. Zahangir Kabbashi, Nassereldeen Ahmed Mirghani, Mohamed Elwathig Saeed
author_sort	Hayyan, Adeeb
title	Pretreatment of Sludge Palm Oil (SPO) for biodiesel production by esterification
title_short	Pretreatment of Sludge Palm Oil (SPO) for biodiesel production by esterification
title_full	Pretreatment of Sludge Palm Oil (SPO) for biodiesel production by esterification
title_fullStr	Pretreatment of Sludge Palm Oil (SPO) for biodiesel production by esterification
title_full_unstemmed	Pretreatment of Sludge Palm Oil (SPO) for biodiesel production by esterification
title_sort	pretreatment of sludge palm oil (spo) for biodiesel production by esterification
publishDate	2008
url	http://irep.iium.edu.my/5519/ http://irep.iium.edu.my/5519/1/adeeb_UKM_Ac1.pdf
first_indexed	2023-09-18T20:14:09Z
last_indexed	2023-09-18T20:14:09Z
_version_	1777407675576877056

Pretreatment of Sludge Palm Oil (SPO) for biodiesel production by esterification

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