Irradiated Sodium–alginate/poly(ethylene oxide) Blend Films Improved by Methyl Acrylate Monomer

Sodium alginate (SA)-based poly(ethylene oxide) (PEO) blend films were improved by methyl acrylate (MA) monomer and γ irradiation toward practical application. The films were prepared by a casting method and modified by glycerol (Gol) and mustard oil (MO). The SA-based films were successfully produc...

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Main Authors: Sumi, Sumaia Aktar, Rahman, Md. Wasikur, Alam, Jahangir, Dafader, Nirmal Chandra, Manir, Serajum, Khan, Maksudur R.
Format: Article
Language:English
Published: Wiley 2016
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/13693/
http://umpir.ump.edu.my/id/eprint/13693/
http://umpir.ump.edu.my/id/eprint/13693/
http://umpir.ump.edu.my/id/eprint/13693/1/Irradiated%20Sodium%E2%80%93alginate-poly%28ethylene%20oxide%29%20Blend%20Films%20Improved%20by%20Methyl%20Acrylate%20Monomer.pdf
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spelling ump-136932017-09-11T07:50:18Z http://umpir.ump.edu.my/id/eprint/13693/ Irradiated Sodium–alginate/poly(ethylene oxide) Blend Films Improved by Methyl Acrylate Monomer Sumi, Sumaia Aktar Rahman, Md. Wasikur Alam, Jahangir Dafader, Nirmal Chandra Manir, Serajum Khan, Maksudur R. TP Chemical technology Sodium alginate (SA)-based poly(ethylene oxide) (PEO) blend films were improved by methyl acrylate (MA) monomer and γ irradiation toward practical application. The films were prepared by a casting method and modified by glycerol (Gol) and mustard oil (MO). The SA-based films were successfully produced with γ irradiation (12 kGy) with 10% PEO, 15% Gol, 20% MO, and 7% MA on a mass basis as optimized. The tensile strength (TS), tear strength (TT), elongation at break (EB), Young's modulus, moisture content, water vapor permeability (WVP), and structural properties of the blended films were determined. The thermal properties of the films were characterized by thermogravimetric analysis, dynamic mechanical analysis, and differential scanning calorimetry, and the structural features were examined with Fourier transform infrared spectroscopy. The ultimate results of this study show a rather remarkable enhancement in the tensile properties (30% TS and 67% TT) and reduction in EB (40%) of the SA-based films with MA addition and γ irradiation. The as-prepared SA-based films demonstrated considerable reductions in the moisture content and WVP and also conferred a desired stability of the films. Wiley 2016 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/13693/1/Irradiated%20Sodium%E2%80%93alginate-poly%28ethylene%20oxide%29%20Blend%20Films%20Improved%20by%20Methyl%20Acrylate%20Monomer.pdf Sumi, Sumaia Aktar and Rahman, Md. Wasikur and Alam, Jahangir and Dafader, Nirmal Chandra and Manir, Serajum and Khan, Maksudur R. (2016) Irradiated Sodium–alginate/poly(ethylene oxide) Blend Films Improved by Methyl Acrylate Monomer. Journal of Applied Polymer Science, 133 (26). pp. 1-10. ISSN 1097-4628 http://dx.doi.org/10.1002/app.43562 DOI: 10.1002/app.43562
repository_type Digital Repository
institution_category Local University
institution Universiti Malaysia Pahang
building UMP Institutional Repository
collection Online Access
language English
topic TP Chemical technology
spellingShingle TP Chemical technology
Sumi, Sumaia Aktar
Rahman, Md. Wasikur
Alam, Jahangir
Dafader, Nirmal Chandra
Manir, Serajum
Khan, Maksudur R.
Irradiated Sodium–alginate/poly(ethylene oxide) Blend Films Improved by Methyl Acrylate Monomer
description Sodium alginate (SA)-based poly(ethylene oxide) (PEO) blend films were improved by methyl acrylate (MA) monomer and γ irradiation toward practical application. The films were prepared by a casting method and modified by glycerol (Gol) and mustard oil (MO). The SA-based films were successfully produced with γ irradiation (12 kGy) with 10% PEO, 15% Gol, 20% MO, and 7% MA on a mass basis as optimized. The tensile strength (TS), tear strength (TT), elongation at break (EB), Young's modulus, moisture content, water vapor permeability (WVP), and structural properties of the blended films were determined. The thermal properties of the films were characterized by thermogravimetric analysis, dynamic mechanical analysis, and differential scanning calorimetry, and the structural features were examined with Fourier transform infrared spectroscopy. The ultimate results of this study show a rather remarkable enhancement in the tensile properties (30% TS and 67% TT) and reduction in EB (40%) of the SA-based films with MA addition and γ irradiation. The as-prepared SA-based films demonstrated considerable reductions in the moisture content and WVP and also conferred a desired stability of the films.
format Article
author Sumi, Sumaia Aktar
Rahman, Md. Wasikur
Alam, Jahangir
Dafader, Nirmal Chandra
Manir, Serajum
Khan, Maksudur R.
author_facet Sumi, Sumaia Aktar
Rahman, Md. Wasikur
Alam, Jahangir
Dafader, Nirmal Chandra
Manir, Serajum
Khan, Maksudur R.
author_sort Sumi, Sumaia Aktar
title Irradiated Sodium–alginate/poly(ethylene oxide) Blend Films Improved by Methyl Acrylate Monomer
title_short Irradiated Sodium–alginate/poly(ethylene oxide) Blend Films Improved by Methyl Acrylate Monomer
title_full Irradiated Sodium–alginate/poly(ethylene oxide) Blend Films Improved by Methyl Acrylate Monomer
title_fullStr Irradiated Sodium–alginate/poly(ethylene oxide) Blend Films Improved by Methyl Acrylate Monomer
title_full_unstemmed Irradiated Sodium–alginate/poly(ethylene oxide) Blend Films Improved by Methyl Acrylate Monomer
title_sort irradiated sodium–alginate/poly(ethylene oxide) blend films improved by methyl acrylate monomer
publisher Wiley
publishDate 2016
url http://umpir.ump.edu.my/id/eprint/13693/
http://umpir.ump.edu.my/id/eprint/13693/
http://umpir.ump.edu.my/id/eprint/13693/
http://umpir.ump.edu.my/id/eprint/13693/1/Irradiated%20Sodium%E2%80%93alginate-poly%28ethylene%20oxide%29%20Blend%20Films%20Improved%20by%20Methyl%20Acrylate%20Monomer.pdf
first_indexed 2023-09-18T22:16:36Z
last_indexed 2023-09-18T22:16:36Z
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