Synthesis, Spectral Characterization and Crystal Structure of (E)-4- Hydroxy-N -(2-methoxybenzylidene) benzohydrazide
A Schiff base, (E)-4-Hydroxy-N -(2-methoxybenzylidene) benzohydrazide, (E4HB) had been synthesized in good yield by the acid-catalyzed condensation methoxybenzaldehyde and 4-hydroxybenzhydrazide in synthesized compound was elucidated by elemental analysis (CHN), FTIR, 13C-NMR and single crystal X-ra...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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AENSI Publishing
2016
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| Subjects: | |
| Online Access: | http://umpir.ump.edu.my/id/eprint/16838/ http://umpir.ump.edu.my/id/eprint/16838/ http://umpir.ump.edu.my/id/eprint/16838/1/fkksa-2016-nhabdurahman-Synthesis%2C%20Spectra.pdf |
| Summary: | A Schiff base, (E)-4-Hydroxy-N -(2-methoxybenzylidene) benzohydrazide, (E4HB) had been synthesized in good yield by the acid-catalyzed condensation methoxybenzaldehyde and 4-hydroxybenzhydrazide in synthesized compound was elucidated by elemental analysis (CHN), FTIR, 13C-NMR and single crystal X-ray diffraction. E4HB crystallized in the crystal system with space group Z = 8, V = 2656.74(10) Å3 14.3951(3) Å, b = 8.7449(2) Å, c =21.1047(4) Å . The crystal structure of the compound is stabilized by intermolecular N1—H1N1….O2, O1 C13—H13A…O1 hydrogen bonds. A π—π interaction with centroid of 3.628 (6) A also occurs (Cg1 = C9— C14, -x, -y, -z). |
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